Supercritical Fluids As Solvents And Reaction Media
Supercritical fluids behave either like a gas or a liquid, depending on the values of thermodynamic properties. This tuning of properties, and other advantageous properties of supercritical fluids led to innovative technologies. More than 100 plants of production size are now in operation worldwide in the areas of process and production technology, environmental applications, and particle engineering. New processes are under research and development in various fields. \ This book provides an...
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Supercritical fluids behave either like a gas or a liquid, depending on the values of thermodynamic properties. This tuning of properties, and other advantageous properties of supercritical fluids led to innovative technologies. More than 100 plants of production size are now in operation worldwide in the areas of process and production technology, environmental applications, and particle engineering. New processes are under research and development in various fields. This book provides an overview of the research activities in the field of Supercritical Fluids in Germany. It is based on the research program "Supercritical fluids as solvents and reaction media" on the initiative of the "GVC-Fachausschuß Hochdruckverfahrenstechnik" (i.e. the German working party on High Pressure Chemical Engineering of the Society of Chemical Engineers).This research program provided an immensely valuable platform for exchange of knowledge and experience. More than 50 young researchers were involved contributing with their expertise, their new ideas, and the motivation of youth. The results of this innovative research are described in this book.- This book provides an overview of the research activities in the field of Supercritical Fluids in Germany- Contains results of projects within the research program on "Supercritical fluids as solvents and reaction media" on the initiative of the German working party on High Pressure Chemical Engineering of the Society of Chemical Engineers.- More than 50 young researchers were involved in contributing with their expertise, their new ideas, and the motivation of youth.
1Phase equilibrium, solubility11.1Experimental determination of phase equilibria and comprehensive examination of the predictive capabilities of group contribution equations of state with a view to the synthesis of supercritical extraction processes31.2Influence of additional components on the solvent power of supercritical ethylene391.3High pressure phase equilibria of copolymer solutions - experiments and correlation611.4Fluid phase equilibria of binary mixtures with supercritical solvents with in-situ concentration measurements by Raman spectroscopy851.5High-pressure solubility measurement of solids in near- and supercritical fluids1211.6Phase behaviour of organic solid solutes and supercritical fluids with respect to particle formation processes1471.7Supercritical carbon dioxide as solvent for organic compounds present in aqueous salt solutions1631.8Correlation and prediction of high-pressure phase equilibria and related thermodynamic properties of simple fluid mixtures1851.9Development of simplified equation of state for molecular fluids and their applications for the investigation of supercritical chain molecule solutions and mixtures2111.10Correlation of the solubility of low-volatile organic compounds in near- and supercritical fluids based on an accurate equation of state2411.11Thermo- and fluiddynamic aspects of the hydrogenation of triglycerides and esters in presence of supercritical fluids2691.12Perturbed-chain-SAFT : development of a new equation of state for simple, associating, multipolar and polymeric compounds2951.13Extractability of As-chelates and solubility of different Rh, Pd-chelates is supercritical fluid CO[subscript 2]3232Properties3412.1P,T-dependence of molecular mobility in supercritical fluids studied by high pressure NMR3432.2Interfacial phenomena in countercurrent and spray processing using supercritical fluids3633Formulation3793.1Synthesis of silica aerogels and their application as drug delivery system3813.2Investigation and modelling of the gas-antisolvent process4293.3Formation of nanoscale drugs by rapid expansion of supercritical solutions (RESS): - experimental and theoretical investigations -4494Extraction4634.1Separation efficiency and axial mixing in packed high pressure extraction columns4654.2Separation of organic compounds from aqueous solutions by means of supercritical carbon dioxide4894.3Supercritical SO[subscript 2] for preparation of sulfur dioxide complexes and for recovery of precious metals from used catalysts5235Reactions5315.1Polymerizations in supercritical carbon dioxide : surfactants, micelle formation, and heterophase polymerization5335.2The kinetics of the early stage of dispersion polymerization in supercritical CO[subscript 2]5595.3Rate coefficients of free-radical polymerization in homogeneous fluid mixtures with carbon dioxide5735.4Ammonia as reagent or reaction medium for polymers5935.5Inorganic materials (metals, ceramics, glasses) under the influence of reactants in supercritical aqueous solutions as well as chemical reactions (partial oxidations, hydrolysis, dehydrations) under the influence of inorganic materials in supercritical aqueous solutions617
\ From the Publisher"Both researchers and students will find the book to be a valuable addition to their library and are certain to gain much insight into the "scientific and engineering fundamentals for new innovative processes using supercritical fluids" as well as their own research topics."\ FLUID PHASE EQUILIBRIA, 2005\ \ \
