Phase Diagrams and Ceramic Processes
Search in google:
Understanding ceramic processes requires simultaneous consideration of the thermodynamics of chemical equilibrium and the kinetic limitations on the attainment of equilibrium imposed through finite atomic mobilities and the probabilistic nature of complex phase formation. The equilibrium phase diagram, its thermodynamic basis and interpretation are considered here as effecting processing decisions in raw materials selection and processes before firing, as well as in optimization of process tempertaures for reaction and sintering for the development of unique microstructures. Consideration of long-term environmental and thermal equilibration are also discussed, particularly in electronic materials for sensor devices as well as conventional refractory applications. Booknews A combined text and reference addressing the use of equilibrium thermodynamics and phase diagrams within the context of ceramic properties and processing. Emphasis is placed on the structural and dielectric properties of oxides and kinetic processes as effecting phase and microstructure development in ceramics. Intended for the graduate and upper level undergraduate student in ceramic engineering and materials science as well as the practicing engineer. Annotation c. by Book News, Inc., Portland, Or.
Preface1Introduction12Products and Properties83Mass Transport for Reaction184From Equilibrium Thermodynamics to Phase Equilibria295The Phase Rule and Heterogeneous Equilibria636One- and Two-Component System Presentations707Three or More Component Equilibria1108Engineered Systems and Oxide Phase Equilibria131References160Suggested Exercises165Index179
