Heterogeneous Kinematics
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This book presents all the theoretical and practical basements of heterogeneous kinetics and reactivity of solids. It applies the new concepts of reactivity and spatial function, introduced by the author, for both nucleation and growth processes, with a unified presentation of the reactivity of bulk and powder solids, including gas-solid reactions, thermal decompositions, solid-solid reactions, reactions of solid solutions, and coalescence of solid grains. It also contains many exercises and problems with solutions included, allowing readers to understand and use all the concepts and methods discussed therein.
Ch. 1 Definitions and experimental approach 1Ch. 2 The real solid : structure elements and quasi-chemical reactions 29Ch. 3 Thermodynamics of heterogenous systems 59Ch. 4 Elementary steps in heterogenous reactions 105Ch. 5 Chemical diffusion 131Ch. 6 Chemical adsorption 169Ch. 7 Mechanisms and kinetics of a process 195Ch. 8 Nucleation of a new solid phase 257Ch. 9 Growth of a solid phase 309Ch. 10 Transformation by surface nucleation and growth 337Ch. 11 Modeling and experiments 379Ch. 12 Granular coalescence 407Ch. 13 Decomposition reactions of solids 449Ch. 14 Reactions between solids 489Ch. 15 Gas-solid reactions 543Ch. 16 Transformations of solid solutions 603Ch. 17 Modeling of mechanisms 651Ch. 18 Mechanisms and kinetic laws 709Ch. 19 Mechanisms and reactivity 779BibliographyIndex
