Catalysis by Polymer-Immobilized Metal Complexes
Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data...
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Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the activity of these catalytic systems and methods of optimizing their control; and specific problems of catalysis by fixed complexes (e.g., ligand exchange and electron transfer in metal polymer systems, macromolecular effects and polyfunctional catalysis). Booknews Presents general information and features of catalysis for a wide range of organic reactions. Pomogailo (polymer chemistry, the Institute of Chemical Physics, Russian Academy of Sciences) covers hydrogenation and oxidation, the polymerization of monomers, dimers, and oligomers. The emphasis is on electro- and photochemical stimulation of catalytic processes in the presence of immobilized catalysts and the specific problems of catalysis by fixed complexes such as ligand exchange and electron transfer in metal polymer systems. Intended for specialists in the field of catalysis and the chemistry of high- molecular compounds and organometallic and coordination chemistry. Annotation c. by Book News, Inc., Portland, Or.
Foreword to English EditionForeword to Russian EditionPreface to English EditionPreface to Russian EditionAbbreviationsIntroduction1Hydrogenation Processes Catalyzed by Metal-Containing Polymers12Oxidation Reactions Catalyzed by Immobilized Metal Complexes873Polymerization Processes Catalyzed by Immobilized Metal Complexes1834Activation of Small Stable Molecules and Stimulation of Catalytic Reactions Through the Participation of Immobilized Complexes2875Specific Features of Catalysis by Immobilized Metal Complexes3476Conclusions375Index385
\ BooknewsPresents general information and features of catalysis for a wide range of organic reactions. Pomogailo (polymer chemistry, the Institute of Chemical Physics, Russian Academy of Sciences) covers hydrogenation and oxidation, the polymerization of monomers, dimers, and oligomers. The emphasis is on electro- and photochemical stimulation of catalytic processes in the presence of immobilized catalysts and the specific problems of catalysis by fixed complexes such as ligand exchange and electron transfer in metal polymer systems. Intended for specialists in the field of catalysis and the chemistry of high- molecular compounds and organometallic and coordination chemistry. Annotation c. by Book News, Inc., Portland, Or.\ \
